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Cryolite (Na3AlF6, sodium hexafluoroaluminate) is an uncommon mineral identified with the once large deposit at Ivigtût on the west coast of Greenland, depleted by 1987. It was historically used as an ore of aluminium and later in the electrolytic processing of the aluminium-rich oxide ore bauxite (itself a combination of aluminium oxide minerals such as gibbsite, boehmite and diaspore). The difficulty of separating aluminium from oxygen in the oxide ores was overcome by the use of cryolite as a flux to dissolve the oxide mineral(s). Pure cryolite itself melts at 1012 °C (1285 K), and it can dissolve the aluminium oxides sufficiently well to allow easy extraction of the aluminium by electrolysis. Substantial energy is still needed for both heating the materials and the electrolysis, but it is much more energy-efficient than melting the oxides themselves. Now, as natural cryolite is too rare to be used for this purpose, synthetic sodium aluminium fluoride is produced from the common mineral fluorite.
Industry:Geology; Mining
Campigliaite is a copper and manganese sulfate mineral with a chemical formula of Cu4Mn(SO4)2(OH)6·4H2O. It has a chemical formula and also a crystal structure similar to niedermayrite, with Cd(II) cation replacing by Mn(II). The formation of campigliaite is related to the oxidation of sulfide minerals to form sulfate solutions with ilvaite associated with the presence of manganese. Campigliaite is a rare secondary mineral formed when metallic sulfide skarn deposits are oxidized. While there are several related associations, there is no abundant source for this mineral due to its rare process of formation. Based on its crystallographic data and chemical formula, campigliaite is placed in the devillite group and considered the manganese analogue of devillite. Campigliaite belongs to the copper oxysalt minerals as well followed by the subgroup M=M-T sheets. The infinite sheet structures that campigliaite has are characterized by strongly bonded polyhedral sheets, which are linked in the third dimension by weaker hydrogen bonds.
Industry:Geology; Mining
Anhydrite is a mineral—anhydrous calcium sulfate, CaSO4. It is in the orthorhombic crystal system, with three directions of perfect cleavage parallel to the three planes of symmetry. It is not isomorphous with the orthorhombic barium (baryte) and strontium (celestine) sulfates, as might be expected from the chemical formulas. Distinctly developed crystals are somewhat rare, the mineral usually presenting the form of cleavage masses. The hardness is 3.5 and the specific gravity 2.9. The color is white, sometimes greyish, bluish, or purple. On the best developed of the three cleavages, the lustre is pearly; on other surfaces it is vitreous. When exposed to water, anhydrite readily transforms to the more commonly occurring gypsum, (CaSO4·2H2O) by the absorption of water. This transformation is reversible, with gypsum or calcium sulfate hemihydrate forming anhydrite by heating to ~200°C under normal atmospheric conditions. Anhydrite is commonly associated with calcite, halite, and sulfides such as galena, chalcopyrite, molybdenite, and pyrite in vein deposits.
Industry:Geology; Mining
Daubréelite is a rare sulfide mineral. It crystallizes with cubic symmetry and has chemical composition of Fe2+Cr3+2S4. It usually occurs as black platy aggregates. Datolite crystallizes in the monoclinic system forming prismatic crystals and nodular masses. The luster is vitreous and may be brown, yellow, light green or colorless. The Mohs hardness is 5.5 and the specific gravity is 2.8 - 3.0. The type localities are in the diabases of the Connecticut River valley and Arendal, Aust-Agder, Norway. Associated minerals include prehnite, danburite, babingtonite, epidote, native copper, calcite, quartz and zeolites. It is common in the copper deposits of the Lake Superior region of Michigan. It occurs as a secondary mineral in mafic igneous rocks often filling vesicles along with zeolites in basalt. Unlike most localities throughout the world, the occurrence of datolite in the Lake Superior region is usually fine grained in texture and possesses colored banding. Much of the coloration is due to the inclusion of copper or associated minerals in progressive stages of hydrothermal precipitation.
Industry:Geology; Mining
Partheite or parthéite is a calcium aluminium silicate and a member of the zeolite group of minerals, a group of silicates with large open channels throughout the crystal structure, which allow passage of liquids and gasses through the mineral. It was first discovered in 1979 in rodingitic dikes in an ophiolite zone of the Taurus Mountains in southwest Turkey. The second discovery occurred in gabbro-pegmatites in the Ural Mountains, Russia. Since its discovery and naming, the chemical formula for partheite has been revised from CaAl2Si2O8•2H2O to include not only water but hydroxyl groups as well. The framework of the mineral is interrupted due to these hydroxyl groups attaching themselves to aluminum centered oxygen tetrahedra. This type of interrupted framework is known in only one other zeolite, the mineral roggianite. As a silicate based mineral with the properties of a zeolite, partheite was first described as zeolite-like in 1984 and listed as a zeolite in 1985. Partheite and lawsonite are polymorphs. Associated minerals include prehnite, thomsonite, augite, chlorite and tremolite.
Industry:Geology; Mining
Allophane is an amorphous to poorly crystalline hydrous aluminium silicate clay mineraloid. Its chemical formula is Al2O3·(SiO2)1.3-2·(2.5-3)H2O. Since it has short-range atomic order, it is a mineraloid, rather than a mineral, and can be identified by its distinctive infrared spectrum and its X-ray diffraction pattern. It was first described in 1816 in Gräfenthal, Thuringia, Germany. Allophane is a weathering or hydrothermal alteration product of volcanic glass and feldspars and sometimes has a composition similar to kaolinite but generally has a molar ratio of Al:Si = 2. It typically forms under mildly acidic to neutral pH (5-7). Its structure has been debated, but it is similar to clay minerals and is composed of curved alumina octahedral and silica tetrahedral layers. Transmission electron micrographs show that it is generally made up of aggregates of hollow spherules ~3-5 nm in diameter. Allophane can alter to form halloysite under resilicating aqueous conditions and can alter to form gibbsite under desilicating conditions. A copper containing variety cupro-allophane has been reported.
Industry:Geology; Mining
Clarkeite is a uranium oxide mineral of composition (Na,Ca,Pb)2(UO2)2(O,OH)3 or (Na,Ca,Pb)(UO2)O(OH)·0-1H2O. Cinnabar is generally found in a massive, granular or earthy form and is bright scarlet to brick-red in color. It occasionally occurs in crystals with a non-metallic adamantine luster. Cinnabar has a rhombohedral bravais lattice, and belongs to the hexagonal crystal system, trigonal division. Its crystals grow usually in a massive habit, though they are sometimes twinned. The twinning in cinnabar is distinctive and forms a penetration twin that is ridged with six ridges surrounding the point of a pyramid. It could be thought of as two scalahedral crystals grown together with one crystal going the opposite way of the other crystal. The hardness of cinnabar is 2–2.5, and its specific gravity 8.1.
Cinnabar resembles quartz in its symmetry and certain of its optical characteristics. Like quartz, it exhibits birefringence. It has the highest refractive power of any mineral. Its mean index for sodium light is 3.08, whereas the index for diamond is 2.42 and that for gallium(III) arsenide (GaAs) is 3.93.
Industry:Geology; Mining
Dollaseite-(Ce) is a sorosilicate end-member epidote mineral and was discovered by Gajer (1927) in the Ostanmossa mine, Norberg district, Sweden, the mineral wrongly named "magnesium orthite" after Gajer (1927) himself was renamed after the structure refinement made to the mineral by Peacor and Dunn (1988) led to the proper classification. The name dollaseite-(Ce) was chosen in honor of Professor Wayne Dollase who performed broad research on the epidote-group minerals. The original confusion of the mineral's composition was because of a complex atomic composition where an exchange of cations leads to a form of dollaseite-(Ce) that at first glimpse resembles an Mg analogue of allanite, now known as dissakisite-(Ce). Dollaseite-(Ce), although not very well known is part of a broad group of minerals, the epidote group which are primarily silicates, the most abundant type of minerals on earth. Dollaseite-(Ce) forms as dark-brown subhedral crystals primarily in Sweden mines. With the ideal chemical formula, CaREE3+Mg2AlSi3O11,(OH)F, dollaseite-(Ce) can be partially identified by its rare content of the REE(rare earth element) Ce.
Industry:Geology; Mining
Anatase is one of the three mineral forms of titanium dioxide, the other two being brookite and rutile. It is always found as small, isolated and sharply developed crystals, and like rutile, a more commonly occurring modification of titanium dioxide, it crystallizes in the tetragonal system; but, although the degree of symmetry is the same for both, there is no relation between the interfacial angles of the two minerals, except in the prism-zone of 45° and 90°. The common pyramid of anatase, parallel to the faces of which there are perfect cleavages, has an angle over the polar edge of 82°9', the corresponding angle of rutile being 56°52½'. It was on account of this steeper pyramid of anatase that the mineral was named, by René Just Haüy in 1801, from the Greek anatasis, "extension", the vertical axis of the crystals being longer than in rutile. There are also important differences between the physical characters of anatase and rutile: the former is less hard (5.5-6 vs. 6-6.5 Mohs) and dense (specific gravity about 3.9 vs. 4.2). Also, anatase is optically negative whereas rutile is positive, and its luster is even more strongly adamantine or metallic-adamantine than that of rutile.
Industry:Geology; Mining
Dolomite is a carbonate mineral composed of calcium magnesium carbonate CaMg(CO3)2. The word dolomite is also used to describe the sedimentary carbonate rock, which is composed predominantly of the mineral dolomite (otherwise known as dolostone).
The mineral dolomite crystallizes in the trigonal-rhombohedral system. It forms white, gray to pink, crystals. Dolomite is a double carbonate, having a different structural arrangement, and it does not rapidly dissolve or effervesce (fizz) in dilute hydrochloric acid. Crystal twinning is common. A solid solution series exists between dolomite and iron rich ankerite. Small amounts of iron in the structure give the crystals a yellow to brown tint. Manganese substitutes in the structure also up to about three percent MnO. A high manganese content gives the crystals a rosy pink color noted in the image above. A series with the manganese rich kutnohorite may exist. Lead and zinc also substitute in the structure for magnesium. The mineral dolomite is closely related to huntite Mg3Ca(CO3)4.
Because dolomite can be dissolved by slightly acidic water, areas of dolomite are important as aquifers and contribute to karst terrain formation.
Industry:Geology; Mining
